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Registro Completo |
Biblioteca(s): |
Embrapa Instrumentação. |
Data corrente: |
01/12/2022 |
Data da última atualização: |
02/12/2022 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Autoria: |
SANTOS, S. R. dos; SCHELLEKENS, J.; SILVA, W. T. L. da; BUURMAN, P.; BOIM, A. G. F.; VIDAL-TORRADO, P. |
Afiliação: |
WILSON TADEU LOPES DA SILVA, CNPDIA. |
Título: |
Selective sorption and desorption of DOM in podzol horizons FTIR and Py-GC/MS of leachates from a column experiment. |
Ano de publicação: |
2022 |
Fonte/Imprenta: |
Science of the Total Environment, v. 826, a154144, 2022. |
Páginas: |
1 - 12 |
ISSN: |
0048-9697 |
DOI: |
http://dx.doi.org/10.1016/j.scitotenv.2022.154144 |
Idioma: |
Inglês |
Conteúdo: |
The sorption of dissolved organic matter (DOM) depends on its interaction with the soil matrix. In hydromorphic podzols, DOM reacts mainly with aluminium (Al), which is responsible for the formation of the Bh-horizon in the subsoil. In this work, we investigated whether the retention of DOM in the soil during the podzolization process is selective in relation to the molecular composition of DOM. A column experiment was conducted to study the selective retention of sorption and desorption processes under controlled conditions. Materials used in the column experiment were representative for Brazilian coastal podzols under tropical rainforest. Materials were collected from this tropical coastal podzol ecosystem, and included soil from E- and Bh-horizons, and DOM from a stream (Stream), peat water (Peat), litter (Litter) and charred litter (Char). To evaluate selective retention of DOM, both the initial DOM and its leachates were analyzed by Fourier transform infrared spectra absorption (FTIR) and pyrolysis gas-chromatography/mass spectrometry (Py-GC/MS). The results showed preferential retention of DOM associated with biopolymers for soil columns with E-horizon material (E), E with Al nitrate (E-n), E with kaolinite (E-k) and E with gibbsite (E-h), except for Char. The composition of leachates after percolation through B horizon columns was mainly determined by desorption, and had a relatively large contribution from phenolic and carboxylic groups associated with Al and low molecular weight aromatic and N-containing pyrolysis products, while products from macromolecular materials such as cellulose were selectively retained in the columns for all DOM types. DOM from the Stream (taken during the rainy season) resembled that of desorbed OM from the B columns, reinforcing substantial desorption in the field as well. Our results suggest that sorption and desorption of OM in the hydromorphic Bh-horizon is continuous and that the selectivity of sorption is dependent on DOM source MenosThe sorption of dissolved organic matter (DOM) depends on its interaction with the soil matrix. In hydromorphic podzols, DOM reacts mainly with aluminium (Al), which is responsible for the formation of the Bh-horizon in the subsoil. In this work, we investigated whether the retention of DOM in the soil during the podzolization process is selective in relation to the molecular composition of DOM. A column experiment was conducted to study the selective retention of sorption and desorption processes under controlled conditions. Materials used in the column experiment were representative for Brazilian coastal podzols under tropical rainforest. Materials were collected from this tropical coastal podzol ecosystem, and included soil from E- and Bh-horizons, and DOM from a stream (Stream), peat water (Peat), litter (Litter) and charred litter (Char). To evaluate selective retention of DOM, both the initial DOM and its leachates were analyzed by Fourier transform infrared spectra absorption (FTIR) and pyrolysis gas-chromatography/mass spectrometry (Py-GC/MS). The results showed preferential retention of DOM associated with biopolymers for soil columns with E-horizon material (E), E with Al nitrate (E-n), E with kaolinite (E-k) and E with gibbsite (E-h), except for Char. The composition of leachates after percolation through B horizon columns was mainly determined by desorption, and had a relatively large contribution from phenolic and carboxylic groups associated with Al and low mol... Mostrar Tudo |
Palavras-Chave: |
DOM-metal binding properties; Natural organic matter; Podzolization; Tropical coastal podzols. |
Categoria do assunto: |
-- |
Marc: |
LEADER 02862naa a2200265 a 4500 001 2149111 005 2022-12-02 008 2022 bl uuuu u00u1 u #d 022 $a0048-9697 024 7 $ahttp://dx.doi.org/10.1016/j.scitotenv.2022.154144$2DOI 100 1 $aSANTOS, S. R. dos 245 $aSelective sorption and desorption of DOM in podzol horizons FTIR and Py-GC/MS of leachates from a column experiment.$h[electronic resource] 260 $c2022 300 $a1 - 12 520 $aThe sorption of dissolved organic matter (DOM) depends on its interaction with the soil matrix. In hydromorphic podzols, DOM reacts mainly with aluminium (Al), which is responsible for the formation of the Bh-horizon in the subsoil. In this work, we investigated whether the retention of DOM in the soil during the podzolization process is selective in relation to the molecular composition of DOM. A column experiment was conducted to study the selective retention of sorption and desorption processes under controlled conditions. Materials used in the column experiment were representative for Brazilian coastal podzols under tropical rainforest. Materials were collected from this tropical coastal podzol ecosystem, and included soil from E- and Bh-horizons, and DOM from a stream (Stream), peat water (Peat), litter (Litter) and charred litter (Char). To evaluate selective retention of DOM, both the initial DOM and its leachates were analyzed by Fourier transform infrared spectra absorption (FTIR) and pyrolysis gas-chromatography/mass spectrometry (Py-GC/MS). The results showed preferential retention of DOM associated with biopolymers for soil columns with E-horizon material (E), E with Al nitrate (E-n), E with kaolinite (E-k) and E with gibbsite (E-h), except for Char. The composition of leachates after percolation through B horizon columns was mainly determined by desorption, and had a relatively large contribution from phenolic and carboxylic groups associated with Al and low molecular weight aromatic and N-containing pyrolysis products, while products from macromolecular materials such as cellulose were selectively retained in the columns for all DOM types. DOM from the Stream (taken during the rainy season) resembled that of desorbed OM from the B columns, reinforcing substantial desorption in the field as well. Our results suggest that sorption and desorption of OM in the hydromorphic Bh-horizon is continuous and that the selectivity of sorption is dependent on DOM source 653 $aDOM-metal binding properties 653 $aNatural organic matter 653 $aPodzolization 653 $aTropical coastal podzols 700 1 $aSCHELLEKENS, J. 700 1 $aSILVA, W. T. L. da 700 1 $aBUURMAN, P. 700 1 $aBOIM, A. G. F. 700 1 $aVIDAL-TORRADO, P. 773 $tScience of the Total Environment$gv. 826, a154144, 2022.
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Embrapa Instrumentação (CNPDIA) |
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Biblioteca(s): |
Embrapa Milho e Sorgo. |
Data corrente: |
30/11/2007 |
Data da última atualização: |
14/03/2016 |
Tipo da produção científica: |
Resumo em Anais de Congresso |
Autoria: |
CANÇADO, G. M. A.; PINEROS, M. A.; MARON, L. G.; SHAFF, J.; CAMARGO, S. R.; MENOSSI, M.; ALVES, V. M. C.; KOCHIAN, L. V. |
Afiliação: |
Gealdo M. A. Cançado, Epamig; Miguel A. Pinerso, Cornell University; Lyza G. Maron, Cornell University; Jon Shaff, Cornell University; Sandra R Camargo, Unicamp; Marcelo Menossi, Unicamp; VERA MARIA CARVALHO ALVES, CNPMS; Leon V. Kochian, Cornell University. |
Título: |
Cloning and characterization of an ALMT1 homologue gene in Maize. |
Ano de publicação: |
2007 |
Fonte/Imprenta: |
In: INTERNATIONAL PLANT & ANIMAL GENOMES CONFERENCE, 15., 2007, San Diego, CA. [Proceedings...]. [S. l.: s.n.], 2007. |
Idioma: |
Inglês |
Thesagro: |
Milho. |
Categoria do assunto: |
-- |
URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/item/35186/1/Cloning-characterization.pdf
https://www.intl-pag.org/15/abstracts/PAG15_P07b_806.html
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Marc: |
LEADER 00632nam a2200193 a 4500 001 1490815 005 2016-03-14 008 2007 bl uuuu u00u1 u #d 100 1 $aCANÇADO, G. M. A. 245 $aCloning and characterization of an ALMT1 homologue gene in Maize.$h[electronic resource] 260 $aIn: INTERNATIONAL PLANT & ANIMAL GENOMES CONFERENCE, 15., 2007, San Diego, CA. [Proceedings...]. [S. l.: s.n.], 2007.$c2007 650 $aMilho 700 1 $aPINEROS, M. A. 700 1 $aMARON, L. G. 700 1 $aSHAFF, J. 700 1 $aCAMARGO, S. R. 700 1 $aMENOSSI, M. 700 1 $aALVES, V. M. C. 700 1 $aKOCHIAN, L. V.
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